Diisoprenyl ether

ABSTRACT

Di(2-methylene-but-3-en-1-yl) ether, methods to make this compound and the use of this compound as a crosslinking agent are disclosed.

This invention relates to a new chemical compound. More particularly, inone aspect of this invention, it relates to a new ether. In anotheraspect, the invention relates to a method to make said ether. In afurther aspect, this invention relates to a process for polymerizingconjugated alkadienes and vinyl substituted aromatic monomers using saidether as a crosslinking agent.

THE INVENTION

It is one object of this invention to provide a new ether.

Another object of this invention is to provide a method to produce thisether.

A further object of this invention is to provide a process forpolymerizing conjugated alkadienes and vinyl-substituted aromaticmonomers in the presence of this ether as a novel crosslinking agent.

These and other objects, embodiments, advantages, details and featuresof this invention will be apparent from the following detaileddescription of the invention, the examples and the appended claims.

By the present invention I have discovered as a new chemical compounddi(2-methylene-but-3-en-1-yl)ether. This ether has the formula ##EQU1##In the following, the compound of this invention is called diisoprenylether. The "isoprenyl" radical, as used herein, is the2-methylene-but-3-en-1-yl radical having the formula ##EQU2##

In accordance with this invention, there is also provided a process forproducing the diisoprenyl ether. The process comprises the steps ofhydrolyzing 2-halomethyl-1,3-butadiene in the presence of stronginorganic base, such as an alkali metal or alkaline earth metalhydroxide. "Halo" is defined to be one member of the group consisting ofchloro, bromo and iodo. The strong alkali metal or alkaline earth metalhydroxide is selected from the group consisting of sodium hydroxide,potassium hydroxide, lithium hydroxide, calcium hydroxide, magnesiumhydroxide, and barium hydroxide. It is presently preferred to react2-chloromethyl-1,3-butadiene with an aqueous solution of sodiumhydroxide such as to produce the diisoprenyl ether. The molar ratio of2-chloromethyl-1,3-butadiene to sodium hydroxide will preferably be inthe range of about 1:3 to 1:4.

It is presently preferred to carry out the process described above inthe presence of a polymerization inhibitor or stabilizer. The functionof this agent is to inhibit polymerization of the diisoprenyl etherformed during the hydrolysis reaction. Any well-known agent thatinhibits the polymerization of alkadienes can be used. Examples of suchinhibitors or stabilizers are phenothiazine, p-phenylene diamine,N-n-octyl-p-phenylene diamine, hydroquinone, 4-tert-butyl-p-cresol,2,6-di-tert-butyl catechol and the like.

In order to improve the yield of this process in accordance with thisinvention, it is also preferred to carry out the hydrolysis of the2-halomethyl-1,3-butadiene in the presence of a phase transfer agent.The function of this phase transfer agent is to facilitate the chemicalreaction between components of the organic liquid phase and componentsof the aqueous liquid phase. Various transfer agents known in the artcan be used for this purpose as long as these agents are compatible withthe reagents used and do not react in an adverse manner with theunsaturated portions of the isoprenyl radicals. Examples of such phasetransfer agents are quaternary ammonium salts, such astricaprylylmethylammonium halogenides, particularlytricaprylylmethylammonium chloride, dodecyltriethylammonium bromide,tetrabutylammonium bromide, and the like. Other transfer agents are thephosphonium salts, such as tetrabutylphosphonium chloride. The anions ofthe quaternary ammonium and phosphonium salts can be selected from thegroup consisting of chloride, bromide, iodide derived from thehydrohalic acids; acetate, benzoate, butyrate and the like derived fromcarboxylic acids, sulfate, hydrogen sulfate and phosphates;benzenesulfonate, p-toluenesulfonate, methanesulfonate and the likederived from sulfonic acids. Preferably, both a phase transfer agent anda polymerization inhibitor are used in the reaction mixture.

The reaction conditions are adjusted such as to keep the reagentsessentially in the liquid phase. Any combination of reaction time andtemperature can be used which is sufficient to bring about substantialhydrolysis without significant loss of product due to side reactionssuch as polymerization. Generally, reactions at 20-80° C for 0.5-40 hr.can be used. Temperatures around 50° C and atmospheric pressures arepresently preferred conditions for the process of hydrolyzing the2-halomethyl-1,3-butadiene with the strong alkali metal or alkalineearth metal hydroxide to give the diisoprenyl ether.

A further embodiment of this invention relates to a polymerizationprocess. In accordance with the process of this invention, monomersselected from the group consisting of conjugated alkadienes andvinyl-substituted aromatic monomers and mixtures of such monomers arepolymerized under emulsion polymerization conditions in accordance withtechnologies well known in the art. However, in accordance with thisinvention, the polymerization emulsion contains diisoprenyl ether as acrosslinking agent. It has been found that the polymers from conjugatedalkadienes produced in accordance with this process exhibit an improvedMooney viscosity compared to polymers produced by the same processcontaining no diisoprenyl ether in the polymerization mixture. Thediisoprenyl ether in accordance with this invention is incorporated asan ingredient in the emulsion of an emulsion polymerization process. Theconditions, as well as the ingredients, initiators, etc. of thisemulsion polymerization process are well known in the art and as such donot constitute a part of this invention. The emulsion polymerizationprocess is, for instance, described in U.S. Pat. No. 2,720,510 issued toA. Rothlisberger and C. Uraneck on Oct. 11, 1955.

The preferred conjugated alkadienes that can be emulsion polymerized inaccordance with this invention in the presence of the diisoprenyl etherhave 4 to about 8 carbon atoms per molecule. Examples of such alkadienesare 1,3-butadiene, isoprene, piperylene, methylpentadiene,2,3-dimethyl-1,3-butadiene and halogen-substituted alkadienes, such aschloroprene and methylchloroprene.

The preferred vinyl-substituted aromatic monomers that can bepolymerized in accordance with this invention in the presence of thediisoprenyl ether contain 8 to about 12 carbon atoms per molecule.Examples are styrene and alpha-methylstyrene, as well as otheralkyl-substituted and halogen-substituted styrenes.

The quantity of the crosslinking compound, namely the diisoprenyl etherin accordance with this invention, used in the polymerization mixturedepends upon the properties of the polymer desired and thus can bevaried in broad ranges. The diisoprenyl ether will, however, usually beemployed in a quantity in the range of about 0.01 to about 10 phm (partsby weight per 100 parts by weight of total monomers), the range of about0.05 to about 2.0 phm being presently preferred.

In the presently preferred emulsion polymerization process of thisinvention, the aqueous emulsion comprises the monomers, an emulsifier, amodifier, an initiator system, and the diisoprenyl ether. In addition tothese compounds which have to be present for the emulsion polymerizationprocess, other components such as activating agents, stabilizers and thelike can also be incorporated into the reaction mixture. Antioxidantscan be added to the final polymer.

Modifying agents for this emulsion polymerization are well known in theart. The function of these modifying agents is to control the molecularweight of the polymer being prepared. Examples for such modifying agentsare mercaptans with 6 to 16, preferably 9 to 14, carbon atoms. The mostpreferred mercaptan modifiers are those of tertiary alkyl configuration,tertiary dodecyl mercaptan being an example. Organic disulfides, such asdiisopropyl xanthogen disulfide, can also be used as modifiers. Amongthe modifying agents, the mercaptans having about 9 to about 14 carbonatoms, more particularly the tertiary dodecyl mercaptans, are presentlypreferred.

Any known emulsifier can be incorporated in the emulsion polymerizationprocess. Examples for such emulsifiers are the metal salts of the fattyacids, e.g. sodium stearate. Usually, the soap is formed in situ, whichmeans that the fatty acid is introduced into the polymerization mixtureand the strong base, such as sodium hydroxide, is added. Thereby thesoap is formed. The emulsifier is used in quantities generally rangingfrom about 1 to about 10 parts by weight per 100 parts by weight ofmonomer.

It is further preferred to include in the emulsion polymerization batchabout 0.1 to about 10 millimols of an oxidant per 100 parts by weight ofthe total monomers. Examples for such oxidants are the organic peroxideshaving 6 to about 16 carbon atoms per molecule, e.g. p-menthanehydroperoxide. The function of this oxidant is that of an oxidizingcomponent in the initiator system which generates free radicals such asfree hydroxyl radicals to initiate the emulsion polymerization.

The emulsion polymerization itself is carried out generally attemperatures of about -20° C to about 70° C. The pressure in thereaction vessel will usually be 0 to about 100 psig. The emulsionpolymerization is usually carried out for about 1 to about 20 hours.

The invention will be more fully understood from the following examples,which constitute preferred embodiments of this invention, but are notintended to limit the scope thereof.

EXAMPLE I Preparation of Diisoprenyl Ether

A mixture of 40 ml water and 9.6 g (0.24 mol) sodium hydroxide wasplaced in a three-necked 100 ml round bottom flask equipped with astirrer, a thermometer, and a water-cooled reflux condenser. The aqueoussodium hydroxide solution was brought to a temperature of 50° C and acharge of 10 g (0.084 mol) 2-chloromethyl-1,3-butadiene, 4.0 g (0.008mol) tricaprylylmethylammonium chloride, commercially available underthe trademark Aliquat 336 from General Mills Corporation, and 0.1 gphenothiazine stabilizer was added to the reaction flask. The reactionmixture was heated under a nitrogen atmosphere with stirring for aperiod of 23 hours.

The two-phase reaction mixture was cooled to room temperature, saturatedwith sodium chloride and extracted four times with 25 ml portions ofether. The ether extracts were separated, combined and washed with 5 mlof a 5 percent aqueous sodium bicarbonate solution. The organic phasewas separated, dried over anhydrous sodium sulfate and distilled to give2.51 g water-white distillate (boiling point 85° C to 50° C as thepressure decreased from 10 to 3 mm) and 4.29 g tarry residue.

The infrared spectrum of the distillate was consistent with thediisoprenyl ether structure. The diisoprenyl ether sample wasredistilled through a 6-inch Vigreux column to give 1.90 g of a producthaving a boiling point of 66° to 67° C at a pressure of about 9 mm. Theyield based on 75 percent conversion of 2-chloromethyl-1,3-butadiene was48 percent. Gas chromatographic analysis of the diisoprenyl etherproduct showed the sample to be 99.1 weight percent pure; the remainderof the sample was 0.9 weight percent of 2-hydroxymethyl-1,3-butadiene.The diisoprenyl ether was stabilized with 0.1 weight percent ofphenothiazine.

The diisoprenyl ether exhibited a refractive index of 1.4902 at 20° Cwith the D line of sodium and possessed a pleasant fruity-pungent odor.The elemental analysis of the diisoprenyl ether sample was:

Calculated for C₁₀ H₁₄ O: C 79.96 percent, H 9.39 percent; Found: C79.20 percent, H 9.50 percent.

The diisoprenyl ether structure was further verified by mass and nuclearmagnetic resonance spectral data.

EXAMPLE II Butadiene-styrene Emulsion Polymerization with DiisoprenylEther as Crosslinking Agent

Into an emulsion polymerization reactor the following components wereintroduced in the quantities shown in the following table; phm meansparts by weight per 100 parts by weight of monomer.

    Components             phm                                                    __________________________________________________________________________    (a)                                                                              Polymerization grade hydrogenated                                             potassium fatty acid salt                                                                         4.6                                                    (b)                                                                              Water (total volume in reaction                                               mixture)            180.0                                                  (c)                                                                              Potassium hydroxide 0.02                                                   (d)                                                                              Potassium chloride  0.30                                                   (e)                                                                              Sodium salts of polymerized alkyl                                             naphthalene sulfonic acids                                                                        0.20                                                   (f)                                                                              Tetrasodium salt of ethylene                                                  diamine tetraacetic acid tetra-                                               hydrate             0.016  (0.35 mmol)                                     (g)                                                                              Styrene             30.0                                                   (h)                                                                              t-Dodecyl mercaptan 0.3202                                                 (i)                                                                              Crosslinking agent (diisoprenyl ether)                                                            0.10                                                   (j)                                                                              Butadiene           70.0                                                   (k)                                                                              p-Menthane hydroperoxide                                                                          0.0625 (0.363 mol)                                     (l)                                                                              Ferrous sulfate heptahydrate                                                                      0.010  (0.036 mmol)                                    (m)                                                                              Sodium formaldehyde sulfoxylate                                               dihydrate           0.050  (0.325 mmol)                                    (n)                                                                              Tetrasodium salt of ethylenediamine                                           tetraacetic acid tetrahydrate                                                                     0.032  (0.070 mmol)                                    (o)                                                                              Sodium dimethyldithiocarbamate                                                                    0.16                                                   (p)                                                                              N-1,3-dimethylbutyl-N'-p-phenylene-                                           diamine             1.0                                                    __________________________________________________________________________

The charge sequence and procedure was as follows: The aqueous soapsolution consisting of components (a) to (f) of the above shown recipewas first introduced into the reactor. Then, the styrene and themercaptan were added, thereafter the crosslinking agent in accordancewith this invention, the diisoprenyl ether, was introduced into thereactor. Then, the butadiene was added. After the addition of thep-menthane hydroperoxide, the reaction mixture was agitated for about 30minutes to lower the temperature of the ingredients to about 5° C. Afterthe addition of the components (l) through (n), the polymerization wascarried out at about 5° C until a conversion of about 60 percent of themonomers was obtained. This was achieved after about 6 hours. Then, thecarbamate (o) was added to stop the reaction and the antioxidant finallywas added to the polymerization product mixture. The latex was creamedby the addition of aqueous sodium chloride solution and the copolymerwas coagulated by the addition of dilute sulfuric acid. The coagulatedcopolymer was isolated by filtration, washed and dried.

After the above described isolation of the copolymer samples, the Mooneyviscosity was determined for copolymer samples prepared as describedabove. The Mooney viscosity, determined in accordance with ASTMD-1646-72 was found to be 571/2 for a copolymer sample prepared inaccordance with the present invention as described in example II.

EXAMPLE III Butadiene-Styrene Copolymerization Without Diisoprenyl Ether

The Example II was repeated with the exception, however, that nodiisoprenyl ether was added to the polymerization mixture. The polymerthus obtained was isolated as described above and the Mooney viscositywas measured. It was found that the Mooney viscosity of this controlpolymer was 191/2. The Mooney viscosity of a polymer reflects itsmolecular weight as well as its rigidity.

A comparison of the two Examples II and III clearly shows that thediisoprenyl ether of this invention greatly increases the Mooneyviscosity which indicates that the diisoprenyl ether acts as acrosslinking agent in this emulsion polymerization process. Thecomparative data are also shown in tabular form in the following table:

                             Mooney                                               Example                  Viscosity                                            ______________________________________                                        III     Control              191/2                                                    (No Crosslinking Agent)                                               II      Invention            571/2                                                    (Diisoprenyl Ether as                                                         Crosslinking Agent)                                                   ______________________________________                                    

It has been found that 1,4-pentadien-3-yl 2,4-pentadien-1-yl ether aswell as di(2,4-pentadien-1-yl)ether were not effective as crosslinkingagents. These isomers to the diisoprenyl ether of this invention werefound to leave the Mooney viscosity of the polymers compared with thecontrol unchanged or even slightly reduced the Mooney viscosity.Therefore, the isoprenyl structure of the pentadienyl radical givenabove is believed to be critical for the effectiveness of thediisoprenyl ether of this invention.

Reasonable variations and modifications which will be apparent to thoseskilled in the art can be made in this invention without departing fromthe spirit and scope thereof.

I claim:
 1. Di(2-methylene-but-3-en-1-yl)ether. 